Unit AGRICULTURAL CHEMISTRY

Course
Agricultural and environmental sciences
Study-unit Code
80783109
Curriculum
Agricoltura sostenibile
Teacher
Daniela Businelli
Teachers
  • Daniela Businelli
Hours
  • 81 ore - Daniela Businelli
CFU
9
Course Regulation
Coorte 2019
Offered
2020/21
Learning activities
Caratterizzante
Area
Discipline della produzione vegetale
Academic discipline
AGR/13
Type of study-unit
Obbligatorio (Required)
Type of learning activities
Attività formativa monodisciplinare
Language of instruction
Italian
Contents
“Agricultural Chemistry” is a discipline that targets both the soil and the plant, as considered to be part of a unitary system that aims to optimize the characteristics of one according to the needs of the other. The course setting is aimed at achieving this goal.
In the plant part, emphasis is placed on the main metabolic processes that take place in it (photosynthesis, C metabolism, lipid and nitrogen metabolism), thus providing students with the basics to be able, in subsequent courses, to understand the nature of the nutritional, water and environmental requirements of the plant and, on the basis of possible abnormalities, to carry out agronomical practices that can correct them.
In the soil part, emphasis is placed on the genesis and chemical composition of its constituents, on the colloidal properties, on the element retention power, soil pH and buffer strength. Finally, factors affecting soil fertility are examined, trying to suggest methods that can minimize any criticality.
Reference texts
L. SCARPONI Elementi di Biochimica Agraria. Galeno Editrice, Perugia, 1985.
R. PINTON et al. (Coordinatori). Fondamenti di biochimica agraria. Patron Editore Bologna, 2016.
LEHNINGER (by Nelson and Cox). Principles of Biochemistry. Freeman and company, New York.
M. BUSINELLI. Chimica del Suolo. Morlacchi editore, Perugia, 2009.
K. TAN Principles of soil chemistry. CRC Press, Boca Raton, London, New York, 2010.
Educational objectives
The main objective of the course is to provide students with the basic knowledge of Agricultural Chemistry, a discipline that covers both the soil and the plant as considered part of a unitary system, and which aims to optimize the characteristics of the one in function of the needs of the other.

The main acquisitions will cover:

1. biological and biochemical context in which each molecule, reaction or metabolic pathway is located.
2. role of enzymes as catalysts of reactions in living organisms.
3. chemical aspects of C's photosynthesis fixation in different plant species.
4. chemical aspects of the main anabolic and catabolic processes of carbohydrates, lipids and proteins.
5. ATP role as a source of energy for metabolic processes
6. importance of coupled reactions for carrying out endoergonic processes in living organisms.
7. chemical assimilation mechanisms of elements necessary for plant development and metabolism.
8. soil as a substrate for plant growth.
9. role of colloids as fertility factors.
10. soil retention power for nutrients.
11. soil ability to retain pollutants by avoiding groundwater contamination.
12. soil resource control in agronomic and environmental field.
13. relationships between soil and plant.
14. soil pH importance in conditioning its nutritional characteristics.
15. soil buffering ability role.

The main skills (i.e. the ability to apply acquired knowledge) will be:
2. role of enzymes as catalysts of reactions in living organisms.
3. chemical aspects of C's photosynthesis fixation in different plant species.
4. chemical aspects of the main anabolic and catabolic processes of carbohydrates, lipids and proteins.
5. ATP role as a source of energy for metabolic processes
6. importance of coupled reactions for carrying out endoergonic processes in living organisms.
7. chemical assimilation mechanisms of elements necessary for plant development and metabolism.
8. soil as a substrate for plant growth.
9. role of colloids as fertility factors.
10. soil retention power for nutrients.
11. soil ability to retain pollutants by avoiding groundwater contamination.
12. soil resource control in agronomic and environmental field.
13. relationships between soil and plant.
14. soil pH importance in conditioning its nutritional characteristics.
15. soil buffering ability role.

The main skills (i.e. the ability to apply acquired knowledge) will be:
- to be able to use a scientific method of investigation, also in relation to application problems.
- to be capable and convincing in exposing their own professional assessments.
- to be able to carry out professional advice concerning fertility and the vulnerability of the soil pollutants.
Prerequisites
In order to understand, interpret and know how to apply theoretical principles and analytical techniques, subject of this course, it is necessary to have successfully passed the “Chemistry” examination (I year). Knowledge of the basic principles of general and organic chemistry is an indispensable prerequisite for the student who wants to attend this course; such preliminary knowledge is also required for non-attending students to be able to successfully undertake the study of the course, using the available teaching material (UNISTUDIUM UNIPG Chimica Agraria).
Teaching methods
The course is organized as follows:
- Lectures on all subjects of the course
- Laboratory exercises at the Agricultural Chemistry Lab concerning: physico-chemical bases of spectrophotometric analyses, enzymatic activity analyses and spectrophotometric determinations of protein content, chlorophylls and carotenes in plant materials. Use of molecular models of silicates. Calcimeters. Soil organic matter and CEC titrimetric determinations. Soil pH determination by potentiometric method. Critical evaluation of soil analysis certificates.
Students (a single group) will follow 6 guided exercises of 2 hours each, preceded by an introduction lecture. At the end of each practical exercise, each student will have to fill out a form reporting his name, data, calculations and results obtained: this form, which will be delivered to the lecturer at the end of the exercise, will allow to verify the student’s participation. This participation, although not mandatory, can affect the final vote.
Other information
Prof. Daniela Businelli Department of Agricultural, Food and Environmental Sciences, DSA3. Agricultural Chemistry Research Unit. Location: New building, ground floor, to the right of the front door.

Tel. 075/5856228
E-mail daniela.businelli@unipg.it
Reception hours: Monday 16.00-17.30, Tuesday 16.00-17.30, Wednesday 16.00-17.30, except in the case of institutional commitments. Receipt by appointment, the request should be made by e-mail
Schedule and lesson time: link to the DSA3 website http://dsa3.unipg.it/didattica/informazioni-per-studenti/

Clipboard, lesson slides and course information are available on the UNISTUDIUM.
https: //www.unistudium.unipg.it/unistudium/

Attendance: Optional, but strongly recommended.
Learning verification modality
The exam is an individual oral test, before which the student is given a pen and papers, where he will write chemical reactions, graphics and everything he thinks fit to expose the subject. The test consists on an interview, of about 20-40 minutes long, aiming to ascertain the knowledge level and the understanding capability acquired by the student on theoretical contents and practical applications as indicated on the course program (i.e. enzymology, photosynthesis, metabolism, lipids, nitrogen cycle, pedogenesis, colloids, soil retention capacity, pH and buffering capacity of the soil). A student may also choose to be examined only on one of the two parts (plant or soil only), completing the test in the following examination dates. The partial test passed has no deadline. The oral test will also verify the student's communication skills and his autonomy in the organization and exposure of topics.

For information on support services for students with disabilities and / or DSA visit the web page http://www.unipg.it/disabilita-e-dsa
Extended program
Agricultural chemistry-
Plant:
Entalpy and entropy. Free energy. Redox potentials. Activation energy. Coupled reactions. Absorption energy and molecular excitation. Enzimology. Photosynthesis. Carbohydrate biosynthesis. Fermentation and respiration processes. Lipid metabolism. Nitrogen cycle. Biochemical bases of plant nutrition.

Agricultural chemistry- Soil:

Soil genesis. The role of hydrosphere, atmosphere and litosphere. Soil carbonates. Soil silicates: structural classification. Weathering and soil development. Genesis of organic fraction. Soil redox potential. Soil colloids. Clays: structural characteristics, properties and development of charge. Soil humus: extraction, fractionation and chemical composition. Oxides and hydroxydes. Soil retention capacity. Reactions of phosphates in soil. Soil pH and buffering capacity. Principles of plant nutrition.

Laboratory practical classes.
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