Unit

Code	A006360
CFU	3
Teacher	Bruno Brunone
Teachers	Bruno Brunone Caterina Capponi (Codocenza) Silvia Meniconi (Codocenza)
Hours	8 ore - Bruno Brunone 8 ore (Codocenza) - Caterina Capponi 8 ore (Codocenza) - Silvia Meniconi
Learning activities	Affine/integrativa
Area	Attività formative affini o integrative
Sector	CEAR-01/A
Type of study-unit	Obbligatorio (Required)

Code	A006359
CFU	3
Teacher	Bruno Brunone
Teachers	Bruno Brunone Caterina Capponi (Codocenza) Silvia Meniconi (Codocenza)
Hours	8 ore - Bruno Brunone 8 ore (Codocenza) - Caterina Capponi 8 ore (Codocenza) - Silvia Meniconi
Learning activities	Affine/integrativa
Area	Attività formative affini o integrative
Sector	CEAR-01/A
Type of study-unit	Obbligatorio (Required)

PHASE EQUILIBRIA IN MULTICOMPONENT SYSTEMS

Code	A005988
CFU	3
Teacher	Alberto Maria Gambelli
Teachers	Alberto Maria Gambelli
Hours	24 ore - Alberto Maria Gambelli
Learning activities	Caratterizzante
Area	Ingegneria dei materiali
Sector	ICHI-02/B
Type of study-unit	Obbligatorio (Required)
Language of instruction	Italian/English
Contents	This course aims to provide the basic knowledge relating to phase equilibia of multicomponent systems necessary for the rational understanding of chemical processes and the unit operations that constitute them with reference to their use in applications of energy interest.
Reference texts	Matteo Maestri. Fondamenti dei processi chimici. Principi di Termodinamica, cinetica e reattoristica chimica applicati allo studio dei processi chimici. Editore: Mc-Graw Hill, Anno 2021, ISBN: 978-8-83 865536-4 J.M. Smith, H.C. Van Ness, M.M. Abbott, Introduction to chemical engineering thermodynamics, Editore: McGraw-Hill, Anno edizione: 2005, ISBN: 978-0-07-124708-5
Educational objectives	The student must demonstrate: a) to possess complete knowledge of multiphase and multicomponent equilibria for the design and analysis of chemical processes and unit operations b) to be able to apply the above knowledge for the quantitative analysis of chemical processes through the resolution of problems concerning mass and energy balances and multicomponent and multiphase equilibria c) to be able to autonomously apply the knowledge covered by the course in solving problems relating to chemical processes
Prerequisites	Basics of thermodynamics and chemistry. Knowledge of the main mathematical functions and operators.
Teaching methods	Theoretical lessons and practical exercises on the topics addressed during the course
Other information	Examination schedule: the examination schedule can be found at the link: http://www.ing1.unipg.it/didattica/studiare/calendario-esami
Learning verification modality	The verification of the educational objectives of the course includes a written and an oral exam.The written exam, lasting three hours, includes two practical exercises relating to the operation of the main industrial chemical plants studied during the course. The oral exam consists of a discussion lasting between 20 and 40 minutes, aimed at ascertaining the level of knowledge of the theoretical and methodological contents provided and detailed in the program. The oral exam also aims to verify the communication and organic synthesis skills, as well as the student's command of language in relation to the theoretical and practical topics covered. The final evaluation will be made in thirtieths by the commission. For information on support services for students with disabilities and/or DSA visit the page http://www.unipg.it/disabilita-e-dsa
Extended program	1. Phase equilibria in multicomponent systems 1.1 General inquiries on phase equilibria. Phase Rule and Duhem Theorem. Liquid-vapour equilibrium: qualitative behavior of binary mixtures. 1.2 Liquid-vapour equilibria in ideal mixtures. Raoult's law and Henry's law. Isothermal and adiabatic flash. 1.3 Real gas mixtures: compressibility factor, equation of the corresponding states. Equations of state of the virial and cubic type. Fugacity coefficients in ideal and real mixtures of real gases. 1.4 Example. Methanol synthesis cycle reactor and condenser. 1.5 Non-ideal mixtures and solutions. Homogeneous and heterogeneous azeotropes.
Obiettivi Agenda 2030 per lo sviluppo sostenibile	7) Clean and affordable energy; 9) Industry, innovation and infrastructure; 12) Responsible consumption and production.

DIFFUSION AND PROCESSING PROCESSES OF THERMOPLASTIC AND THERMOSETTING POLYMERS

Code	A005991
CFU	3
Teacher	Luigi Torre
Teachers	Marco Rallini (Codocenza) Luigi Torre
Hours	12 ore (Codocenza) - Marco Rallini 12 ore - Luigi Torre
Learning activities	Caratterizzante
Area	Ingegneria dei materiali
Sector	IMAT-01/A
Type of study-unit	Obbligatorio (Required)
Language of instruction	Italian
Contents	The course will face the main aspects of the characteristics, properties and technologies of polymeric materials. Starting from the basis and from the chemical-physical characteristics of polymeric materials, the synthesis processes of polymers.
Reference texts	Fondamenti di struttura, proprietà e tecnologia dei polimeri a cura di Enrico Pedemonte http://nuovacultura.it/catalogo/fondamenti-struttura-proprieta-tecnologia-dei-polimeri/ R. J. Young and P.A. Lowel: Indroduction to Polymers. Chapman ed. F. Rodriguez: “Principles of Polymer Systems” Mc Graw Hill.
Educational objectives	Provide the student with an in-depth knowledge of the main characteristics of polymeric materials, and on their industrial production. Being able to understand the production process used for polymeric products and know the physical and mechanical properties of polymers and plastics.
Prerequisites	Math and advanced math, physics and chemistry
Teaching methods	Video lessons and lectures. During the lectures, exercises will also be done on problems related to the various topics.
Learning verification modality	The examination for obtaining the open badge consists of solving exercises on the topics covered. Earning the open badge will allow the student to access the final cluster examination. For information about support services for students with disabilities and/or specific learning disorders (SLDs), please visit the page at http://www.unipg.it/disabilita-e-dsa.
Extended program	General rules for solubility Solubility parameters Hansen theory Flory–Huggins theory Models for mass absorption and transport Introduction, flows, and processes Parameters affecting flow and flow instabilities Extrusion Injection molding Film formation Fiber spinning Processing of thermosetting materials (thermosets)

RHEOLOGY AND VISCOELASTICITY OF POLYMERS

Code	A005990
CFU	3
Teacher	Luigi Torre
Teachers	Marco Rallini (Codocenza) Luigi Torre
Hours	12 ore (Codocenza) - Marco Rallini 12 ore - Luigi Torre
Learning activities	Caratterizzante
Area	Ingegneria dei materiali
Sector	IMAT-01/A
Type of study-unit	Obbligatorio (Required)
Language of instruction	Italian
Contents	The course will face the main aspects of the characteristics, properties and technologies of polymeric materials. Starting from the basis and from the chemical-physical characteristics of polymeric materials, the synthesis processes of polymers.
Reference texts	Fondamenti di struttura, proprietà e tecnologia dei polimeri a cura di Enrico Pedemonte http://nuovacultura.it/catalogo/fondamenti-struttura-proprieta-tecnologia-dei-polimeri/ R. J. Young and P.A. Lowel: Indroduction to Polymers. Chapman ed. F. Rodriguez: “Principles of Polymer Systems” Mc Graw Hill.
Educational objectives	Provide the student with an in-depth knowledge of the main characteristics of polymeric materials, and on their industrial production. Being able to understand the production process used for polymeric products and know the physical and mechanical properties of polymers and plastics.
Prerequisites	Math and advanced math, physics and chemistry
Teaching methods	Video lessons and lectures. During the lectures, exercises will also be done on problems related to the various topics.
Learning verification modality	The examination for obtaining the open badge consists of solving exercises on the topics covered. Earning the open badge will allow the student to access the final cluster examination. For information about support services for students with disabilities and/or specific learning disorders (SLDs), please visit the page at http://www.unipg.it/disabilita-e-dsa.
Extended program	Viscoelasticity: definitions and typical time-dependent behaviors Maxwell model Voigt model Other viscoelastic models Boltzmann superposition principle Dynamic mechanical analysis (DMA) Time–temperature superposition Rheology: introduction to flow behavior Introduction to viscometry Newtonian analysis of category A viscometers Category B viscometers: capillary Category B viscometers: Couette Other types of viscometers Non-Newtonian fluids Non-Newtonian capillary viscometry Examples of viscosity measurement and melt flow index Introduction to thermal analysis DTA/DSC TMA

THERMODYNAMICALLY CONTROLLED REAGENT SYSTEMS: CHEMICAL EQUILIBRIUM

Code	A005989
CFU	3
Teacher	Alberto Maria Gambelli
Teachers	Alberto Maria Gambelli
Hours	24 ore - Alberto Maria Gambelli
Learning activities	Caratterizzante
Area	Ingegneria dei materiali
Sector	ICHI-02/B
Type of study-unit	Obbligatorio (Required)
Language of instruction	English/Italian
Contents	This course aims to provide the basic knowledge relating to thermodynamics of reacting systems necessary for the rational understanding of chemical processes and the unit operations that constitute them with reference to their use in applications of energy interest.
Reference texts	Matteo Maestri. Fondamenti dei processi chimici. Principi di Termodinamica, cinetica e reattoristica chimica applicati allo studio dei processi chimici. Editore: Mc-Graw Hill, Anno 2021, ISBN: 978-8-83 865536-4 J.M. Smith, H.C. Van Ness, M.M. Abbott, Introduction to chemical engineering thermodynamics, Editore: McGraw-Hill, Anno edizione: 2005, ISBN: 978-0-07-124708-5
Educational objectives	The student must demonstrate: a) to possess complete knowledge of the principles of thermodynamics for the design and analysis of chemical processes and unit operations b) to be able to apply the above knowledge for the quantitative analysis of chemical processes through the resolution of problems concerning mass and energy balances and chemical equilibria of reacting systems c) to be able to autonomously apply the knowledge covered by the course in solving problems relating to chemical processes
Prerequisites	Basics of thermodynamics and chemistry. Knowledge of the main mathematical functions and operators.
Teaching methods	Theoretical lessons and practical exercises on the topics addressed during the course
Other information	Examination schedule: the examination schedule can be found at the link: http://www.ing1.unipg.it/didattica/studiare/calendario-esami
Learning verification modality	The verification of the educational objectives of the course includes a written and an oral exam.The written exam, lasting three hours, includes two practical exercises relating to the operation of the main industrial chemical plants studied during the course. The oral exam consists of a discussion lasting between 20 and 40 minutes, aimed at ascertaining the level of knowledge of the theoretical and methodological contents provided and detailed in the program. The oral exam also aims to verify the communication and organic synthesis skills, as well as the student's command of language in relation to the theoretical and practical topics covered. The final evaluation will be made in thirtieths by the commission. For information on support services for students with disabilities and/or DSA visit the page http://www.unipg.it/disabilita-e-dsa
Extended program	1. Material and energy balances in stoichiometrically controlled reagent systems (combustion) 1.1 Stoichiometry requests. Reagent excess and deficiency. Stoichiometric evaluations. 1.2 Material balances on stoichiometrically controlled processes. Composition and analysis of exhausts. 1.3 Thermochemistry of combustion reactions. Heating value of fuels and heat of reaction. Hess's law. 1.4 Energy balances on combustion processes. Adiabatic flame temperature. Combustion efficiency. 2. Thermodynamically controlled reagent systems: Chemical equilibrium 2.1 Equilibrium condition for reacting systems. Gibbs free energy and chemical potential. Fugacity and activity. Reference states for pure and mixed gaseous and condensed systems. Standard free energy and equilibrium constant. Effects of temperature and pressure on equilibrium composition: Kirchhoff's law and Van't Hoff equation. Degree of advancement, selectivity conversion and yield. 2.2 Material and energy balances in simple and complex reacting systems. Calculation of equilibrium conversion and adiabatic reaction temperature. 2.3 Thermodynamic analysis applied to hydrogen production chain processes.
Obiettivi Agenda 2030 per lo sviluppo sostenibile	7) Clean and affordable energy; 9) Industry, innovation and infrastructure; 12) Responsible consumption and production.